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Name : Urmimala Maitra

Department : School of Materials Sciences
Designation : Assistant Professor
Contact : +91 33 2473 4971 (Ext 1224)
Email : urmimala.maitra@iacs.res.in


Home

Our group is interested in fundamental science of ionically conducting solids for developing high-energy and high-power batteries like Li-, Na- ion and all solid-state batteries. Specifically, we focus on synthesis of electrodes and solid electrolytes, study their crystal structure, electronic and surface properties, identify redox mechanisms and mechanisms of failure/degradation aimed at improved batteries. The group is also interested in using ion-conducting solids for use in other applications such as next generation metal-oxygen batteries, supercapacitors, electrochromic windows and sensors.    

 


Academic Profile

2020 - Current    Assistant Professor, Indian Association for Cultivation of Sciences, Kolkata, India


2019 - 2020       Research Fellow, Max Planck Institute of Microstructure Physics, Halle, Germany

                           Advisor: Prof. Stuart Parkin

2018 - 2019       Research Fellow, Justus Liebig University Gießen, Germany

                           Advisor: Prof. Jürgen Janek

2015 - 2018       Post Doctoral Researcher and group leader Na-ion team

                           Materials Department, University of Oxford, Oxford, U.K.

                           Advisor: Prof. Peter G. Bruce

2010 - 2014       Ph. D (Materials Science) Chemistry and Physics of Materials Unit, JNCASR, India

                          Advisor: Prof. C. N. R. Rao


Group


Research Associate

Dr. Subham Ghosh

NPDF
PhD - JNCASR
M.Sc. - IIT Bombay
Research - Development of Material for Next-generation Li-ion and Na-ion Batteries
Email - smssg2683@iacs.res.in
Extn. - 1216
Google Scholar


PhD student

Amit Ghoshal

JRF
M.Sc. – JNCASR
B.Sc. - Vivekananda Mahavidyalaya, Burdwan
Research Area - High Voltage Cobalt free Redox Cathodes for Next-Generation Na/Li-Ion Batteries  
Email – smsag2525@iacs.res.in
Lab Extn. - 1216
Sayandeep Guin

SRF
M.Sc. – IACS (Int.PhD)
B.Sc. - Serampore College
Research Area – Li-excess Disordered rocksalt oxides as Next-generation High Energy cathode Material for Li-ion Batteries
Email – smssg2177@iacs.res.in
Lab Extn. - 1216
Kheyali De

JRF
M.Sc. - IIEST, Shibpur
B.Sc. - Midnapore College (Autonomous)
Research Area – Li Disordered rocksalt oxides as Next-generation High Energy cathode Material for Li-ion Batteries
Email - smskd2917@iacs.ac.in
Lab Extn. - 1216
Susmita Pramanik

JRF
M.Sc. – IACS (Int.PhD)
B.Sc. - Midnapore College (Autonomous)
Research Area – Na Disordered rocksalt oxides as Next-generation High Energy cathode Material for Na-ion Batteries
Email – smssp2636@iacs.res.in
Lab Extn. - 1216
Susim Sabuj Sarkar

JRF
Five Year Integrated M.Sc. - ISERC, Visva Bharati
Email - smsss3058@iacs.res.in
Lab Extn. - 1216


Project Student

Utsab Sarkar

Master's Project Student
M.Sc. – IACS, Kolkata
B.Sc. - Surendranath College, Kolkata
Email - smsus2791@iacs.res.in
Extn. - 1216


Alumni



Post Doctoral Fellow

* Dr. Amit Kumar Das, RA-II (2021-23), PhD – NIT Durgapur, Google Scholar

Project Students

*Sudipta Kundu, Project Student (2022-23), M.Sc. - IACS
Current Position - PhD Student at The Pennsylvania State University, U.S.A.


Short-Term Project Students

* Alapan Samanta (Jun-Sept 2023), M.Sc. - Banaras Hindu University
Current Position - PhD Student at Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR)

* Riddhika Chattopadhyay (Apr - Jun 2023), M.Sc. - IIT Madras

* Ankita Mondal (April - July 2023) , M.Sc. - Behala college, Calcutta University


Publication

Representative publications

Maitra, U.*Das, A. K., Oxygen Redox Intercalation Cathodes: The Fundamentals and Strategies to Resolve the Challenges, ACS Appl. Energy Mater., 2022, 5, 4522

Boivin, E., House, R. A., Pérez-Osorio, M. A., Marie, J. J., Maitra, U., Rees, G. J., Bruce P. G.*, Bulk O2 formation and Mg displacement explain O-redox in Na0.67Mn0.72Mg0.28O, Joule, 2021, 5, 1267

Sun, B. Xiong, P. Maitra, U., Langsdorf, D. Yan, K. Wang, C., Janek, J., Schröder, D.*, Wang G.*, Design Strategies to Enable the Efficient Use of Sodium Metal Anodes in High Energy Batteries, Adv. Mater., 2020, 32, 1903891.

House, R. A., Maitra, U., Pérez-Osorio, M. A., Lozano, J. A., Jin, L. Somerville, J. W. Duda, L. C. Nag, A., Walters, A. Zhou, A. J. Roberts, M. R.,  Bruce  P. G.*, Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes, Nature, 2020, 577, 502.

Somerville, J. W., Sobkowiak, A. Tapia-Ruiz, A., Billaud, J. House, R.A., Ericsson, T. Häggström, L. Roberts, M. R., Villevieille, C., Maitra, U., Bruce P. G.*, Nature of the “Z”-phase in charged P2-type Na-ion battery cathodes, Energy. Environ. Sci., 2019, 12, 2223. 

House, R. A., Maitra, U.Jin, L., Somerville, J. W., Lozano, J. G., Rees, N. H., Duda, L. C., Massel, F., Chadwick, A. V, Ramos, S., Roberts, M. R., Bruce, P. G.* What Triggers Oxygen Loss in Oxygen Redox Cathode Materials? Chem. Mater., 2019, 31, 3293.

Maitra, U., House, R. A., Somerville, J. W., Tapia-Ruiz, N., Lozano, J. G., Guerrini, N., … Bruce, P. G.*. Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2Nature. Chem., 2018, 10, 288.

Tapia-Ruiz, N., Dose, W. M., Sharma, N., Chen, H., Heath, J., Somerville, J., Maitra, U., Islam, M. S.*, Bruce, P. G.* High voltage structural evolution and enhanced Na-ion diffusion in P2-Na2/3Ni1/3-xMgxMn2/3O2 (0 ≤ x ≤ 0.20), cathodes from diffraction, electrochemical and ab-initio studies. Energy Environ. Sci., 2018,11,1470.

Somerville, J. W., House, R. A., Tapia-Ruiz, N., Sobkowiak, A., Ramos, S., Chadwick, A. V., …Maitra, U.Bruce, P. G.*. Identification and characterization of high energy density P2-type Na2/3[Ni1/3−y/2 Mn2/3−y/2Fey]O2 compounds for Na-ion batteries. J. Mater. Chem. A, 2018, 6, 5271. 

House, R. A., Jin, L., Maitra, U., Tsuruta, K., Somerville, J. W., Förstermann, D. P., … Bruce, P. G.* Lithium manganese oxyfluoride as a new cathode material exhibiting oxygen redox. Energy Environ. Sci., 2018, 11, 2. 

Singh, G., Tapia-Ruiz, N., Lopez Del Amo, J. M., Maitra, U., Somerville, J. W., Armstrong, A. R., … Bruce, P. G.* High Voltage Mg-Doped Na0. 67Ni0. 3–xMgxMn0.7O(x= 0.05, 0.1) Na-Ion Cathodes with Enhanced Stability and Rate Capability. Chem. Mater., 2016, 28, 5087. 

Maitra, U., Gupta, U., De, M., Datta, R., Govindaraj, A., & Rao, C. N. R.* Highly effective visible-light-induced H2 generation by single-layer 1T-MoS2 and a nanocomposite of few-layer 2H-MoS2 with heavily nitrogenated graphene Angew. Chemie Int. Ed., 2013, 52, 13057. 

Maitra, U., Govindaraj, A., & Rao, C. N. R.* Importance of trivalency and the eg1 configuration in the photocatalytic oxidation of water by Mn and Co oxides. Proc. Natl. Acad. Sci. USA, 2013, 110, 11704.

Rao, C. N. R.*, Ramakrishna-Matte H. S. S., Maitra, U., Graphene Analogues of Inorganic Layered Materials. Angew. Chem. Int. Ed. 2013, 52, 13162.

 


Open Positions

Interested Ph.D and Post Doctoral candidates are encouraged to apply. Please send an email enquiry with your CV.


Research Activities

Sustainable electricity production and storage are critical to address the greatest threat facing us toady i.e. climate change. Therefore, almost 200 years after the discovery of ion conducting solids by Michael Faraday, today there is renewed interest in studying ionic and mixed (ion & electron) conductors for applications in batteries, fuel cells and supercapacitors. Thrust areas of our work are discussed below.

Co free High-energy-density Li and Na ion battery cathodes

We investigate cathodes that utilize the redox of the oxide ion to provide high energy density while being free from expensive elements like Co.

 

                                               

 

Inexpensive sustainable cathodes

We explore safe, sustainable, inexpensive cathode materials composed of Na or multi-valent ion ions (like Mg2+, Ca2+ and Zn2+) and polyanionic materials etc. as a high energy density yet cost effective alternative to Li-ion batteries. We optimize their performance based on their electronic properties and structural phase transitions.

Mechanisms

We utilize in-situ and ex-situ structural and spectroscopic characterization to determine the redox mechanisms, failure and degradation mechanisms and develop design strategies for improved performance

 

                                                                   

 

Solid Electrolytes and Solid-state battery

We investigate solid electrolytes for liquid free solid- state batteries that have huge potential for high energy density, safe, non-flammable, thin, fast charging batteries. 

 


Instrumental Facilities




Pellet Maker




Planetary Ball Mill with milling jar




Battery Cycler




Glove Box




Vacuum Oven




Calendering Machine




Muffle Furnace




Tube Furnace




Magnetic Stirrer (x2)




Fume Hood




Sonicator




Vacuum drying tube




Weighing Balance