Our research group has been involved in the area of synthetic inorganic chemistry toward designing of proficient strategies to achieve synthesis and characterization of unusual transition metal complexes, relevant structural-functional model systems for important enzyme active sites and discovering unusual reactivity with a goal to expand the scope of synthetic inorganic chemistry as well as bioinorganic chemistry.
The specific areas of interest include:
Professional Positions:
October 2021 till date: Professor at IACS, Kolkata, India
August 2018 to October 2021: Associate Professor at IACS, Kolkata, India
August 2013 to August 2018: Assistant Professor at IACS, Kolkata, India.
September 2011 to July 2013: Postdoctoral Associate at MIT with Prof. Stephen J. Lippard
February 2009 to August 2011: Postdoctoral Associate at Harvard University with Prof. Richard H. Holm
Education:
Ph.D. (2009): Indian Institute of Technology Kanpur, India. (Advisor: Prof. Sabyasachi Sarkar)
M.Sc. (2002): University of Calcutta, India.
B.Sc. (2000): Ramakrishna Mission Residential College, Narendrapur, University of Calcutta, India.
Hossain, K.; Basak, A.; Majumdar, A.* J. Am. Chem. Soc. 2025, 147, 15408-15428
Atta, S.; Mandal, A.; Patra, S.; Majumdar, A.* Inorg. Chem. 2025, 64, 7726-7745
Karmakar, S.; Patra, S.; Halder, R.; Karmakar, S.; Majumdar, A.* Inorg. Chem. 2024, 63, 23202–23220
Atta, S.; Mandal, A.; Majumdar, A.* Inorg. Chem. 2024, 63, 15161-15176
Karmakar, S.; Patra, S.; Pramanik, K.; Adhikary, A.; Dey, A.;* Majumdar, A.* Inorg. Chem. 2024, 63, 8537-8555
44. "Nonheme Binuclear Transition Metal Complexes with Hydrosulfide and Polychalcogenides" Hossain, K.; Atta, S.; Chakraborty, A.; Karmakar, S.; Majumdar, A.* Chem. Commun. 2024, 60, 4979-4998
43. "Carboxylate Bridged Binuclear Cobalt(II) Complexes Catalyze the Hydrolysis of Thiolates to Alcohols" Chakraborty, A. B.; Ganguly, T.; Bera, A.; Majumdar, A.* Eur. J. Inorg. Chem. 2024, 27, e202400105
42. "Kinetic Isotope Effect Offers Selectivity in CO2 Reduction" Patra, S.; Atta, S.; Ghosh, S.; Majumdar, A.;* Dey, A.* Chem. Commun. 2024, 60, 4826-4829
41. "Generation and Reactivity of Polychalcogenide Chains in Binuclear Cobalt(II) Complexes" Hossain, K.; Roy Choudhury, A.; Majumdar, A.* JACS Au. 2024, 2, 771–787.
Atta, S.; Mandal, A.; Saha, R.; Majumdar, A.* Dalton Trans. 2024, 53, 949-965 (Dalton Transactions HOT Articles)
39. "Transition Metal Mediated Hydrolysis of C-S Bonds: An Overview of a New Reaction Strategy" Ganguly, T.; Chakraborty, A. B.; Majumdar, A.* ACS Org. Inorg. Au 2023, 3, 332-349
Chakraborty, A. B.; Ganguly, T.; Majumdar, A.* Inorg. Chem. 2023, 62, 11095-11111
37. "Redox Convergent Synthesis and Reactivity of a Cobalt(III)-pentasulfido Compound" Atta, S.; Majumdar, A.* Chem. Eur. J. 2023, 29, e202203579
36. "Catalytic Hydrolysis of Thiolates to Alcohols" Ganguly, T.; Bera, A.; Chakraborty, A. B.; Majumdar, A.* Inorg. Chem. 2022, 61, 7377-7386
|
|
Naskar, T.; Jana, M.; Majumdar, A.* J. Mol. Struct. 2022, 1262, 133041
|
|
34. "Polysulfido Chain in Binuclear Zinc(II) Complexes" Hossain, K.; Majumdar, A.* Inorg. Chem. 2022, 61, 6295-6310
|
|
Pal, N.; Naskar, T.; Majumdar, A.*, Inorg. Chim. Acta. 2022, 531,120738
|
|
32. "Synthesis and Redox Reactions of Binuclear Zinc(II)-thiolate Complexes with Elemental Sulfur" Naskar, T.; Pal, N.; Majumdar, A.*, New. J. Chem. 2021, 45, 22406-22416
|
|
31. "Reduction of NO by Diiron Complexes in Relation to Flavodiiron Nitric Oxide Reductases" Pal, N.; Jana, M.; Majumdar, A.* Chem. Commun. 2021, 57, 8682-8698 Chemical Communications Hot Articles.
|
|
Pal, N,; White, C.J.; Demeshko, S.; Meyer, F.; Lehnert, N.;* Majumdar, A.* Inorg. Chem. 2021, 60, 15890- 15900 ("Renaissance in NO Chemistry" special issue)
|
|
29. "Thiolate Coordination vs. C-S Bond Cleavage of Thiolates in Dinickel(II) Complexes" Das, A.; Ganguly, T.; Majumdar, A.* Inorg. Chem. 2021, 60, 944–958
|
|
|
|
Bond Cleavage Step Precedes the S-S Bond Cleavage Step" Ganguly, T.; Majumdar, A.* Inorg. Chem. 2020, 59, 4037-4048
|
|
Ganguly, T.; Das, A.; Majumdar, A.* Inorg. Chem. 2019, 58, 9998-10011
|
|
Pal, N.; Majumdar, A.* DaltonTrans. (Themed issue: Bioinspired Reactivity and Coordination Chemistry) 2019, 48, 5903-5908
|
|
24. "Cobalt(II) Mediated Desulfurization of Thiophenes, Sulfides and Thiols". Ganguly, T.; Das, A.; Jana, M.; Majumdar, A.* Inorg. Chem., 2018, 57, 11306-11309 (Most Read Articles)
|
|
23. “C–S Bond Cleavage, Redox Reactions and Dioxygen Activation by Nonheme Dicobalt(II) Complexes” Jana, M.; Majumdar, A.* Inorg. Chem. 2018, 57, 617-632.
|
|
Jana, M.; Pal, N.; White, C. J.; Kupper, C.; Meyer, F.; Lehnert, N.*; Majumdar A.* J. Am. Chem. Soc. 2017, 139, 14380-14383
|
|
Khatua, S.; Naskar, T.; Nandi, C.; Majumdar, A.* New. J. Chem. 2017, 41, 9769-9783
|
|
20. “Model Compounds for Mo-Nitrate Reductases” in "Metalloenzymes in Denitrification: Applications and Environmental Impacts". Royal Society of Chemistry, Metallobiology Series, Eds. Moura, I.; Moura, J. J. G., Co-Eds. Pauleta, S. R.; Maia, L. November, 2016, Chapter 8, p. 170-184 Majumdar, A.; Sarkar, S.*
|
|
Khatua, S.; Majumdar, A.* J. Mol. Struct. 2016, 1120, 267-273
|
|
Pal, N.; Majumdar, A.* Inorg. Chem. 2016, 55, 3181-3191
|
|
Khatua, S.; Majumdar, A.* J. Inorg. Biochem. 2015, 142, 145-153
|
|
Majumdar, A.* Dalton Trans. 2014, 43, 12135-12145
|
|
Majumdar, A.* Dalton Trans. 2014, 43, 8990-9003
|
|
14. “Light-induced N2O production from a nonheme iron-nitrosyl dimer”. Jiang, Y.; Hayashi, T.; Matsumura, H.; Do, L. H.; Majumdar, A.; Lippard, S. J.*; Moënne-Loccoz, P.* J. Am. Chem. Soc. 2014, 136, 12524−12527 |
|
13. “Versatile Reactivity of a Solvent-Coordinated Diiron(II) Compound: Synthesis and Dioxygen Reactivity of a Mixed Valent FeIIFeIII Species”. Majumdar, A.; Apfel, U.-P.; Jiang,Y.; Moënne-Loccoz, P.; Lippard, S. J.* Inorg. Chem. 2014, 53, 167-181 |
|
12. “Mononitrosyl Non-HemeDiiron Complexes: Importance of Iron Oxidation State in Controlling the Extent of Nitrosylation”. Majumdar, A.; Lippard, S. J.* Inorg. Chem. 2013, 52, 13292-13294 |
|
11. “Bioinorganic Chemistry of Molybdenum and Tungsten Enzymes: A Structural-Functional Modelling Approach”. Majumdar, A.; Sarkar, S.* Coord. Chem. Rev. 2011, 255, 1039-1054 |
|
10. “Comparative Molecular Chemistry of Molybdenum and Tungsten and Its Relation to Hydroxylase and Oxotransferase Enzymes”. Holm, R. H.*; Solomon, E. I.*; Majumdar, A.; Tenderholt, A. Coord. Chem. Rev. 2011, 255, 993-1015 |
|
9. “Specific Incorporation of Chalcogenide Bridge Atoms in Molybdenum/Tungsten-Iron Sulfur Single Cubane Clusters”. Majumdar, A.; Holm. R. H.* Inorg. Chem. 2011, 50, 11242-11251 |
|
8. “Stabilization of 3:1 Site-Differentiated Cubane-Type Clusters in the [Fe4S4]1+ Core Oxidation State by Tertiary Phosphine Ligation: Synthesis, Core Structural Diversity and S = ½ Ground States”. Deng, L.; Majumdar, A.; Lo, W.; Holm. R. H.* Inorg. Chem. 2010, 49, 11118–11126 |
|
7. “Reactions of MonodithioleneTungsten(VI) Sulfido Complexes with Copper(I) in Relation to the Structure of the Active Site of Carbon Monoxide Dehydrogenase”.Groysman, S.; Majumdar, A.; Zheng, S-L.; Holm.R. H.* Inorg. Chem. 2010, 49, 1082-1089 |
|
6. “Mixed Ligand Tris Chelate Complexes of Molybdenum (IV) and Tungsten (IV): A Comparative Experimental and Theoretical Study”. Majumdar, A.; Sarkar. S.* Inorg. Chim.Acta. 2009, 362, 3493-3501 |
|
5. “Necessity of Fine Tuning in Mo(IV) Bis(Dithiolene) Complexes to Warrant Nitrate Reduction”. Majumdar, A.; Pal, K.; Sarkar. S.* Dalton Trans. 2009,1927-1938 |
|
4. “Mono-oxo Bis(dithiolene) Mo(IV) / W(IV) Complexes as Building Blocks for Sulfide Bridged Bi and Tri-Nuclear Complexes”. Majumdar, A.; Mitra, J.; Pal, K.; Sarkar. S.* Inorg. Chem. 2008, 47, 5360 – 5364 |
|
3. “Selectivity of Thiolate Ligand and Preference of Substrate in Model Reactions of Dissimilatory Nitrate Reductase”.Majumdar, A.; Pal, K.; Sarkar. S.* Inorg. Chem. 2008, 47, 3393 – 3401 |
|
2. “Desoxo Molybdenum(IV) and Tungsten(IV) bis(dithiolene) Complexes: Monomer Dimer Interconversion Involving Reversible Thiol Bridge Formation". Majumdar, A.; Pal, K.; Nagarajan, K.; Sarkar , S.* Inorg. Chem. 2007, 46, 6136 – 6147 |
|
1. “Chemistry of [Et4N][MoIV(SPh)(PPh3)(mnt)2] as an Analogue of Dissimilatory Nitrate Reductase with its Inactivation on Substitution of Thiolate By Chloride”. Majumdar, A.; Pal, K.; Sarkar. S.* J. Am. Chem. Soc. 2006, 128, 4196 – 4197 |
Postgraduate Course (previously integrated PhD course):
PhD Course:
PhD 07: Concepts, Models and Techniques in Chemistry (in 2016)
Extramural Fundings:
29. Mr. Diptorup Chakraborty (M.S. IIT Kanpur, Summer Project, 15th May-15th July, 2025)
28. Ms. Akanksha Jha (M.Sc. Summer Project, Lady Brabourne College, 15th April-15th June, 2025)
27. Ms. Lipika Baral (M.S. IACS, One Year Project, July 2024-May 2025)
26. Ms. Srimayee Mukherjee (M.S. IISER Berhampur, July 2024-May, 2025)
25. Ms. Diya Ray (B.Sc., St. Xavier’s College, 5th June, 2024-14th July, 2024)
24. Ms. Bibhabori Ghosh (M.Sc. Summer Project, Lady Brabourne College, 16th April-30th June, 2024)
23. Ms. Shreya Chowdhury (M.Sc., Behala College, 1st September, 2023-18th March, 2024)
22. Ms. Suchismita Karmakar (BS-MS, IACS, Two Years Project, June 2023-May2025)
21. Mr. Rajib Hazra (MS, IIT KGP, Summer Project, 3rd May-5th July, 2023)
20. Ms. Ankita Das (M.Sc. Summer Project, Lady Brabourne College, 10th April-10th June, 2023)
19. Mr. Rahul Saha (Int. Ph.D. IACS, One Year Project, 2022-2023)
18. Ms. Suchismita Karmakar (BS-MS, Sem-IV, IACS, Summer Project, May 2022-July 2022)
17. Ms. Amina Khatun (M.Sc. Summer Project, Lady Brabourne College, 15th March-24th May, 2022)
16. Ms. Ananya Hati (Int. Ph.D. IACS, One Year Project, 2021-2022)
15. Ms. Asima Maji (Int. Ph.D. IACS, One Year Project, 2020-2021)
14. Ms. Anindita Ghosh (Int. Ph.D. IACS, One Year Project, 2019-2020)
13. Mr. Jyotiprokash Biswas (M.Sc. University of Calcutta, July 2019-March, 2020)
12. Ms. Pallavi Kundu (M.Sc. Summer Project, Central University of Jharkhand, May-July, 2019)
11. Ms. Priyanka Saha (M.Sc. Summer Project, Lady Brabourne College, April-May, 2019)
10. Mr. Shuvajit Ghosh (M.Sc. Summer Project, IIT Hyderabad, May-July, 2018)
9. Ms. Kuheli Dutta (M.Sc. Summer Project, IIT Kanpur, May-July, 2018)
8. Mr. Sudip Baguli (M.Sc. Summer Project, R. K. M. R. C. Narendrapur, March-April, 2018)
7. Ms. Satarupa Das (BS-MS Dual Degree, IISER Kolkata, May-July, 2017)
6. Mr. Monojit Nandi (BS-MS Dual Degree, IISER Bhopal, May-July, 2017)
5. Mr. Anindya Roy (M.Sc. Summer Project, IIT Hyderabad, May-July, 2017)
4. Ms. Anindita Sasmal (M.Sc. Summer Project, Behala College, March-April, 2017)
3. Mr. Chandan Nandi (M.Sc. Summer Project, R. K. M. R. C. Narendrapur, March-April, 2017)
2. Mr. Partha Bhattacharyya (M.Sc. Summer Project, R. K. M. R. C. Narendrapur)
1. Mr. Pallab Modak (Int. Ph.D. IACS, One Year Project)
16. 11th Asian Biological Inorganic Chemistry Conference (AsBIC11) during during 1st-6th December, 2024 at Guilin, China.
15. Recent Advances in Chemical Sciences (RACS 2024) during during 7th-9th November, 2024 at IIEST Shibpur, India.
14. International Conference on Catalysis (IC²) during 11th-13th March, 2024 at IACS, Kolkata, India.
13. 6th Symposium on Advanced Biological Inorganic Chemistry (SABIC-2024) during 7th-11th January, 2024 at Kolkata, India.
12. Modern Trends in Inorganic Chemistry (MTIC)-XX during 14th-17th December, 2023 at IISc Bangalore, India.
11. 10th Asian Biological Inorganic Chemistry Conference (AsBIC10) during 28th November-3rd December, 2022 at Kobe, Japan.
10. Inorganic Chemistry Discussion Meeting on 15th January, 2020 at IISER Kolkata.
9. Indo-French Symposium on "Small Molecule Activation for Fuels and Commodity Chemicals Production" during
November 27-29, 2019 at IACS, Kolkata, India.
8. 19th International Conference on Biological Inorganic Chemistry (ICBIC-19) during August 11-16, 2019 in Interlaken,
Switzerland.
7. 'Metal ions in Biology' on 24th June, 2019 at St. Xavier's College (Autonomous), Kolkata, India.
6. National Conference on Functional Molecules (NCOFM-2019) on 30th March, 2019 at University of Calcutta, India.
5. 9th Asian Biological Inorganic Chemistry Conference (AsBIC-9) during 9th-14thDecember, 2018 in Singapore.
4. Modern Trends in Inorganic Chemistry (MTIC)-XVII during 11th-14th December, 2017 at Pune, India.
3. In House Symposium at IACS, Kolkata, India in March, 2017.
2. 5th Symposium on Advanced Biological Inorganic Chemistry (SABIC 2017) during 7th - 11th January, 2017 at Kolkata, India.
1. Indo-French seminar on 'Bio-inorganic Approaches to Current Health Problems' during March 24 - 28, 2014 at Pondicherry University, Pudhucherry, India.